SrAl12O19

Strontium hexaaluminate · Sr-beta-alumina

Strontium hexaaluminate is a thermally robust, insulating oxide ceramic used primarily as a stable support material in high-temperature catalytic systems.

Crystal structure of SrAl12O19 (hexagonal, P63mc (No. 186))
Ground-state structure · Materials Project
Overview

About Strontium hexaaluminate

Strontium hexaaluminate is a structurally complex oxide that functions as a wide-gap insulator. Its robust thermodynamic stability makes it a highly reliable candidate for demanding industrial environments where structural integrity under thermal stress is paramount.

Because of its refractory nature, this material is primarily utilized in high-temperature catalytic processes and as a stable ceramic substrate. Its ability to maintain its phase identity at elevated temperatures allows it to serve as a long-lasting support for active catalytic species.

At a glance

Key Properties

Cross-validated computational properties for Strontium hexaaluminate, aggregated across 2 databases.

Band Gap

4.46 eV
Range across DFT structures

Energy Above Hull

0.002 eV/atom
Best (lowest) across sources

Stability

Near hull (likely stable)
1 DFT source

Structures

3
2 databases, 2 space groups
Crystallography

Reported Structures

Lowest-energy structures reported for SrAl12O19, ranked by energy above hull.

Space GroupCrystal SystemBand Gap (eV)E above hull (eV/atom)E/atom (eV)Density (g/cm³)
P63mc (No. 186)hexagonal4.460.0023-7.8343.92
P63/mmc (No. 194)hexagonal4.450.0028-7.8333.91
P63/mmc (No. 194)
Uses

Applications

Where Strontium hexaaluminate is used.

High-temperature catalytic supportsRefractory ceramicsThermal barrier coatingsPhosphor host materials
Reference

Frequently Asked Questions

Common questions about Strontium hexaaluminate, answered from cross-validated data.

What is SrAl12O19?

Strontium hexaaluminate is a thermally robust, insulating oxide ceramic used primarily as a stable support material in high-temperature catalytic systems.

More questions
What is SrAl12O19 used for?
Strontium hexaaluminate (SrAl12O19) is used in high-temperature catalytic supports, refractory ceramics, thermal barrier coatings, and phosphor host materials.
What is the band gap of SrAl12O19?
Strontium hexaaluminate (SrAl12O19) has a DFT-computed band gap of 4.46 eV across 3 reported structures.
Is SrAl12O19 a metal, semiconductor, or insulator?
With a wide band gap up to 4.46 eV it is an insulator / wide-band-gap material.
Is SrAl12O19 thermodynamically stable?
Strontium hexaaluminate (SrAl12O19) has a lowest energy above hull of 0.002 eV/atom (near hull (likely stable)).
What is the crystal structure of SrAl12O19?
The lowest-energy reported polymorph of Strontium hexaaluminate (SrAl12O19) is hexagonal symmetry, space group P63mc (No. 186).
What is the density of SrAl12O19?
The computed density of the ground-state structure of Strontium hexaaluminate (SrAl12O19) is 3.92 g/cm³.
How many polymorphs of SrAl12O19 are known?
3 structures of SrAl12O19 are reported across 2 databases, spanning 2 distinct space groups.
What elements does SrAl12O19 contain?
Strontium hexaaluminate (SrAl12O19) contains Al, O, and Sr (3 elements).
Where does the data for SrAl12O19 come from?
SrAl12O19 data is cross-referenced from materials_project, jarvis.
Comparison

How It Compares

Within the spinel oxide catalysts class.

Unlike transition metal-based oxides such as CuO or NiO, which are often prized for their redox activity and electronic conductivity, SrAl12O19 acts as a chemically inert and thermally stable insulator, similar to the role played by MgAl2O4 or Al2O3 in high-temperature catalyst support systems.

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Related Compounds

Other Spinel Oxide Catalysts in the database.

Data sources & attribution
  • materials_project — Data from the Materials Project. Cite: Jain et al., APL Materials 1, 011002 (2013).
  • jarvis — Data from JARVIS (NIST). Cite: Choudhary et al., npj Comp. Mater. 6, 173 (2020).

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